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**Detailed Q&A on Inner Layer Browning/Black Oxide Defects in PCBs**

Time:2026-02-27 Views:1

**Q1: What is browning used for? What's its relationship with bubbles?**

**A:** Browning is used to create a micro-roughness + passivation on the inner layer copper surface, allowing the prepreg (PP) resin to firmly "grip" the board. Poor roughening → Poor wettability → Resin cannot spread → Air cannot escape → Bubbles.


**Q2: What are the signs of poor browning?**

**A:**

- Mottled, dark, or uneven surface appearance

- Water marks, fingerprints, oil stains

- Poor bonding strength, delamination after thermal shock

- Regular patterned bubbles in large areas


**Q3: Which browning issues are most likely to cause bubbles?**

**A:**

- **Insufficient roughening:** Surface too smooth, poor grip.

- **Excessive roughening:** Copper layer becomes loose and prone to detachment.

- **Incomplete cleaning:** Oil/grease prevents resin adhesion.

- **Inadequate drying:** Residual moisture turns into bubbles.


**Q4: Which is more prone to bubbles, black oxide or browning?**

**A:** The black oxide layer is thicker and theoretically offers stronger bonding, but if not controlled well, it's more prone to delamination and bubbles. Browning is now more commonly used for high-reliability boards.


**Q5: What happens if inner layers are stored for too long?**

**A:** Oxidation, moisture absorption, and contamination occur, all leading to bubbles + delamination. General requirement: Lamination within 24~48 hours after inner layer fabrication.


**Q6: How to optimize the pretreatment process most effectively?**

**A:**

- Sequence: Cleaning → Water Rinse → Micro-etching → Water Rinse → Forced Air Drying

- Ensure thorough drying and no water marks.

- Avoid touching the board surface.


**Q7: How to quickly judge if browning is qualified?**

**A:**

- Visually uniform appearance.

- No water marks, no stains.

- No delamination after thermal shock test.

- Good bonding interface observed in microsection analysis.


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Bubbles aren't always caused by the lamination process itself; many are "lost at the starting line." Getting the browning process right directly increases the success rate of lamination.

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